✦ LIBER ✦

“Micellar” catalysis in the aqueous intermolecular diels-alder reaction: rate acceleration and enhanced selectivity

✍ Scribed by Paul A. Grieco; Philip Garner; Zhen-min He

Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 192 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)81800-6

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✦ Synopsis

The intermolecular Diels-Alder reactions employing dienophiles k and 2 with diene < have been examined in water. The significantly enhanced rates, as well as the improved selectivity observed in water stand in sharp contrast to the results observed in hydrocarbon solvents:

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