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Iminium Ion Catalysis: Use of the α-Effect in the Acceleration of the Diels—Alder Reaction

✍ Scribed by Julie L. Cavill; Jens-Uwe Peters; Nicholas C. O. Tomkinson

Publisher
John Wiley and Sons
Year
2003
Weight
89 KB
Volume
34
Category
Article
ISSN
0931-7597

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The Effect of Pressure on Retro Diels–Al
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✍ Frank-Gerrit Klärner; Volker Breitkopf 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 333 KB 👁 2 views

The activation and reaction volumes (∆V /∆V) were showing negative volumes of activation (∆V Ͻ 0) whereas the others are slightly retarded (∆V Ͼ 0). From the analysis determined for the retro Diels-Alder reactions of the parent dihydrobarrelene 1a, its 2-cyano derivative 1b, the exo and of the volum