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Rate constants for radical recombination. III. The trifluoromethyl radical

✍ Scribed by R. Hiatt; S. W. Benson

Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
289 KB
Volume
4
Category
Article
ISSN
0538-8066

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✦ Synopsis

Products of the radical reactions arising from t-BuZOz, CFsI, and CHsI at 146Β°C in the vapor phase have been measured over a 33-fold range of CHsI/CH,I ratios and shown to be governed by the rapidly established equilibrium

Together with K estimated by thermochemical methods, the results yield, for the rate of recombination for CF3. radicals, k, = * 0 . 5 M-' sec-l.

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