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The ultraviolet absorption spectrum of tert-butyl radicals and the rate constant for their recombination

✍ Scribed by D.A. Parkes; C.P. Quinn

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
633 KB
Volume
33
Category
Article
ISSN
0009-2614

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📜 SIMILAR VOLUMES

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## Abstract The decay of photochemically generated __tert__‐butyl radicals in methylcyclopentane solutions containing chloroform is studied by time‐resolved ESR spectroscopy. In the pure solvent it perfectly follows the second‐order rate law for radical self‐termination. Increasing chloroform conce

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## Abstract Intrinsic spectral and kinetic parameters have been measured for the ethyl radical, which was formed in the gas phase by the flash photolysis of azoethane. Absolute values of the extinction coefficient ϵ(λ) were derived from complementary measurements of the yield of nitrogen and the ab