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Rate constants for alkyl radical recombination. II. The isopropyl radical

✍ Scribed by R. Hiatt; S. W. Benson

Publisher: John Wiley and Sons
Year: 1972
Tongue: English
Weight: 280 KB
Volume: 4
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550040203

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✦ Synopsis

Products of radical combination from the free-radical buffer system R' + R'I RI + R'. have been analyzed for the two cases, R = Me, R' = iPr and R = Et, R' = iPr.

Results are consistent with the previously examined system where R = Me, R' = Et, and give a value of k p for iPr' combination of 108.6*1.' M-1 sec-l.

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