Rate constant for the reaction CH3+CH2(X̃3B1) at 298 K
✍ Scribed by R. Deters; M. Otting; H. Gg. Wagner; F. Temps; S. Dóbé
- Book ID
- 112008929
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1998
- Tongue
- English
- Weight
- 320 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0372-8323
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📜 SIMILAR VOLUMES
The absolute rate constant for the reaction of N ("S) with CH, has been determined at 298 K in a discharge flow system coupled with collision-free sampling mass spectrometty at low electron energies. The rate constant was determined under pseudo-firstorder conditions with [N] > [ CH,]. The result is
Excess molar volumes at the temperature 298.15 K were measured for , and {xCH3(CH2)4 CH3 +(1x)CH3(CH2)3OH}. Excess molar volumes were determined using an Anton Paar DMA 60/602 densimeter. The experimental values obtained in this work were compared with results obtained using methods which estimate
Excess molar enthalpies at the temperature 298.15 K were measured for CH2)n-2CH3}, (n = 10, 12), using a Calvet microcalorimeter. The experimental results were compared with those calculated by using the Nitta-Chao, UNIFAC I, and UNIFAC II models.