Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co
A rate constant for CH2(3B1) + CH3
β Scribed by M.J. Pilling; J.A. Robertson
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 379 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The Laser PhotolysisβShock Tube technique coupled with Hβatom atomic resonance absorption spectrometry has been used to study the reaction, H + CH~4~ β CH~3~ + H~2~, over the temperature range, 928β1697 K. Shockβtube studies on the reverse of this reaction, CH~3~ + H~2~ β H + CH~4~, usi
measuring the relative CO qilantum yields from kctenc photolysis as a function of photolysis wavelength WC have determined the threshold energy at X0 for C112CO('AI) -+CHH(33~i) + CO(t -+ \, ) to be 75.7 + 1.0 kcal/mole. This corrc-SpOl'ldS to a VdlC Of 40.7 f 1.0 kcal/molc for &Hpzss[ C112(3B,)]. B
Disproportionation/combination rate constant ratios, k , / k , , have been measured for the collision between CF3CH2CH2 and CF3 radicals to be 0.022 ? 0 002 and for CF3CH2CH2 and CF3CH2CH2 radicals to be 0.100 IT 0.002. Comparison to previous work from this laboratory for the reaction of CF3CH2CHCI
The rate constants for the reactions of OH radicals with CH 3 OCF 2 CF 3 , CH 3 OCF 2 CF 2 CF 3 , and CH 3 OCF(CF 3 ) 2 have been measured over the temperature range 250-430 K. Kinetic measurements have been carried out using the flash photolysis, laser photolysis, and discharge flow methods combine