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Rate Constant for the Recombination Reaction CH 3 + CH 3 → C 2 H 6 at T = 298 and 202 K

✍ Scribed by Cody, Regina J.; Payne,, Walter A.; Thorn,, R. Peyton; Nesbitt, Fred L.; Iannone, Mark A.; Tardy, Dwight C.; Stief, Louis J.


Book ID
126792723
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
91 KB
Volume
106
Category
Article
ISSN
1089-5639

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The absolute rate constant for the reaction of N ("S) with CH, has been determined at 298 K in a discharge flow system coupled with collision-free sampling mass spectrometty at low electron energies. The rate constant was determined under pseudo-firstorder conditions with [N] > [ CH,]. The result is