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Excess molar enthalpies of {x1CH3CH2COOCH2CH3+x2CH3(CH2)4CH3+ (1 −x1−x2)CH3(CH2)v−2CH3}, (v= 10, 12), at the temperature 298.15K

✍ Scribed by M. López; E. Carballo; C. Franjo; J. Salgado; J. Vijande; J.L. Legido

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
504 KB
Volume
27
Category
Article
ISSN
0021-9614

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✦ Synopsis

Excess molar enthalpies at the temperature 298.15 K were measured for CH2)n-2CH3}, (n = 10, 12), using a Calvet microcalorimeter. The experimental results were compared with those calculated by using the Nitta-Chao, UNIFAC I, and UNIFAC II models.

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Excess molar enthalpies at the temperature 298.15 K were measured for CH2)nCH3} (n = 9, 12), and {x2CH3(CH2)4CH3 + (1-x2)CH3(CH2)n-2CH3} (n=9, 12), using a Calvet microcalorimeter. The experimental results were compared with those calculated by using the Nitta-and-Chao model.

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## Excess molar volumes at CH2 )n-2CH3}, (n= 10 or n = 12), and {xCH3(CH2)3CH2Cl + (1x)CH3(CH2)n-2CH3}, (n= 10 or n = 12), were determined using a densimeter Anton Paar DMA 60/602. All the experimental values were compared with the results obtained by empirical expressions for estimating ternar

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Excess molar volumes at the temperature 298.15 K of the ternary mixtures: , and of the binary mixtures: , and {xCH3(CH2)5OH + (1-x)Cl(CH2)5CH3} were determined using a densimeter. All the experimental values were compared with the results obtained by empirical expressions for estimating ternary pr

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Excess molar volumes V E m of the ternary mixture {x1CH3(CH2)3OH+x2CH3(CH2)4CH3 + (1-x1-x2)CH3(CH2)3NH2} at the temperatures 298.15 K and 313.15 K, and the binary mixtures {xCH3(CH2)3OH + (1-x)CH3(CH2)3NH2}, {xCH3(CH2)4CH3 + (1-x)CH3(CH2)3NH2} at T=313.15 K have been determined from density measurem