Preparation of [tris(1,3-dithiole-2-thione-4,5-dithiolato)antimonate(1−)] complexes, [Sbv(dmit)3]−. Crystal structure of the 1,4-dimethylpyridinium salt
✍ Scribed by Gavin M. Spencer; James L. Wardell; John H. Aupers
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 357 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0277-5387
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📜 SIMILAR VOLUMES
The 1,3-dithiole-2-thione-4,5-dithiolate (dmit) ligand and chalcogen atom substituted isologs have been extensively used in organic and coordination chemistry since their first reported synthesis in 1975. Over approximately the past 8 years a number of diverse and interesting dmit coordination compl
## Abstract The preparation and single crystal growth of bis(tetrabutylammonium)bis(4,5‐dithiolato‐1,3‐dithiole‐2‐thione)copper, (I), are described. The energy gap Eg of (I) is about 2.38 eV. The nonlinear optical susceptibility χ^(3)^ is about 1.3×10^‐3^ esu at 1064 nm. The characterization of (I)