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Diorganotin 1,3-dithiole-2-thione-4,5-dithiolate compounds, R2Sn(dmit): the crystal structure of MePhSn(dmit)

โœ Scribed by Solange M.S.V. Doidge-Harrison; John T.S. Irvine; Abdullah Khan; Gavin M. Spencer; James L. Wardell; John H. Aupers


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
611 KB
Volume
516
Category
Article
ISSN
0022-328X

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The 1,3-dithiole-2-thione-4,5-dithiolate (dmit) ligand and chalcogen atom substituted isologs have been extensively used in organic and coordination chemistry since their first reported synthesis in 1975. Over approximately the past 8 years a number of diverse and interesting dmit coordination compl

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Three kinds of the 1:1 Ni(dmit) 2 salts with 4-(4-pyridyl)pyridinium (PP), 4-[2-(4-pyridyl)ethenyl]pyridinium (P]P), and 4-[2-(4-pyridyl)ethyl]pyridinium (P-P) cations have been prepared and structurally characterized. All of these crystals are composed of a multi-dimensional network of the Ni(dmit)