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The coordination chemistry of 1,3-dithiole-2-thione-4,5-dithiolate (dmit) and isologs

โœ Scribed by Anthony E. Pullen; Ruth-Maria Olk

Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
531 KB
Volume
188
Category
Article
ISSN
0010-8545

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โœฆ Synopsis

The 1,3-dithiole-2-thione-4,5-dithiolate (dmit) ligand and chalcogen atom substituted isologs have been extensively used in organic and coordination chemistry since their first reported synthesis in 1975. Over approximately the past 8 years a number of diverse and interesting dmit coordination complexes have been described. Also, dmit and isologs have been used in a variety of material applications, including in superconducting charge-transfer and radical anion salts. The synthesis, structures and properties of a selection of these compounds will be presented and discussed covering the literature from 1991 to approximately mid-1998.

๐Ÿ“œ SIMILAR VOLUMES

Charge Carrier Doping in the Ni(dmit)2 S
Charge Carrier Doping in the Ni(dmit)2 Simple Salts by Hydrogen-Bonding Pyridinium Cations (dmit=1,3-dithiol-2thione-4,5-dithiolate)
โœ Takeshi Hirose; Hiroyuki Imai; Toshio Naito; Tamotsu Inabe ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 417 KB

Three kinds of the 1:1 Ni(dmit) 2 salts with 4-(4-pyridyl)pyridinium (PP), 4-[2-(4-pyridyl)ethenyl]pyridinium (P]P), and 4-[2-(4-pyridyl)ethyl]pyridinium (P-P) cations have been prepared and structurally characterized. All of these crystals are composed of a multi-dimensional network of the Ni(dmit)