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Preparation, single crystal growth and characterization of bis(tetrabutylammonium)bis(4,5-dithiolato-1,3-dithiole-2-thione)copper

✍ Scribed by X. Q. Wang; D. Xu; Q. Ren; G. H. Zhang; X. B. Sun; X. Q. Hou; W. F. Guo; H. Lü

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
150 KB
Volume
42
Category
Article
ISSN
0232-1300

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✦ Synopsis

Abstract

The preparation and single crystal growth of bis(tetrabutylammonium)bis(4,5‐dithiolato‐1,3‐dithiole‐2‐thione)copper, (I), are described. The energy gap Eg of (I) is about 2.38 eV. The nonlinear optical susceptibility χ^(3)^ is about 1.3×10^‐3^ esu at 1064 nm. The characterization of (I) has been performed by electronic absorption, infrared and X‐ray powder diffraction spectroscopy. The thermal behavior of (I) has been investigated by means of thermogravimetric analysis (TGA) and differential thermal analysis (DTA) measurements in air. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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