## Abstract The preparation and single crystal growth of bis(tetrabutylammonium)bis(4,5‐dithiolato‐1,3‐dithiole‐2‐thione)copper, (I), are described. The energy gap Eg of (I) is about 2.38 eV. The nonlinear optical susceptibility χ^(3)^ is about 1.3×10^‐3^ esu at 1064 nm. The characterization of (I)
Crystal growth, morphology, spectrographic characterization and thermal properties of 4,5-bis(benzoylthio)-1,3-dithiole-2-thione
✍ Scribed by Xinqiang Wang; Dong Xu; Guanghui Zhang; Quan Ren; Weiliang Liu
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 211 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0232-1300
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✦ Synopsis
Abstract
Single crystals of 4,5‐bis(benzoylthio)‐1,3‐dithiole‐2‐thione (BBDT), were grown from methylene chloride and the growth morphology was deduced by the Bravais–Friedel Donnay–Harker (BFDH) model. The grown crystals were characterized by optical absorption, infrared, Raman and X‐ray powder diffraction spectroscopy. The thermal behavior of BBDT has been investigated by means of thermogravimetric analysis and differential thermal analysis measurements in air. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
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