Thermal decomposition kinetics of tetraalkylammonium and dimethylpyridinium salts of the complex anion bis(1,3-dithiole-2-thione-4,5-dithiolate) bismuthate (−1)
✍ Scribed by Ana Maria Rocco; James L. Wardell; Robson Pacheco Pereira
- Publisher
- Springer Netherlands
- Year
- 2011
- Tongue
- English
- Weight
- 558 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0022-5215
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The electron impact ionization mass spectra of 4,5-bis(alkylthio)-l,3dithiole-2-thiones and their 1,'tdithiole-3thione isomers were studied by accurate mass measurements and linked scans. The relative abundance of ions formed following the extrusion of S, , CS or CS, allows an unambiguous isomer dif
The 1,3-dithiole-2-thione-4,5-dithiolate (dmit) ligand and chalcogen atom substituted isologs have been extensively used in organic and coordination chemistry since their first reported synthesis in 1975. Over approximately the past 8 years a number of diverse and interesting dmit coordination compl