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Preparation of 35S-labelled xanthates and 35S-labelled carbon disulphide by exchange reactions

✍ Scribed by J. Cífka; V. Vinš

Publisher
John Wiley and Sons
Year
1965
Tongue
French
Weight
326 KB
Volume
1
Category
Article
ISSN
0022-2135

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✦ Synopsis

The order of the exchange reaction between potassium ethyl xanthate and elemental sulphur was determined. A mixture of ethanol and toluene was used as the solvent for the routine preparation of 35S-labelled ethyl, n-butyl, n-hexyl and n-octyl xanthates at a temperature of 200 C. The dependence of the exchange rate on the presence of water was observed. The decomposition of 35s-labelled ethyl xanthate in dilute hydrochloric acid was used for the preparation of labelled carbon disulphide.

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