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Preparation and structure of a novel methano[60]fullerene containing a stable P-ylid

โœ Scribed by Hiroshi Yamaguchi; Shizuaki Murata; Takeshi Akasaka; Toshiyasu Suzuki

Book ID
104257056
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
125 KB
Volume
38
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

A novel methanofullerene containing a stable phosphorous ylid is obtained from a reaction of fullerene (C60) with a 1:1 mixture of triphenylphosphine and dimethyl acetylenedicarboxylate.

๐Ÿ“œ SIMILAR VOLUMES

ChemInform Abstract: Preparation and Str
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Preparation and Structure of a Novel Methano(60)fullerene Containing a Stable P-Ylide. -Heating of C60-fullerene with PPh3 and dimethyl acetylenedicarboxylate in toluene gives the title compound in 61% yield, existing as 3:2 mixture of two rotational isomers. -(YAMAGUCHI,

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The reaction of [60]fullerene with a dimethylsulfonium a-formylalkylide gave a novel methano[60]fullerene having a formyl group at the bridge-head carbon. This 2,2-[60]fulleroalkanal was readily converted into a variety of N-aryl-2,2-[60]fulleroaldimines by condensation with aromatic amines; one of