ChemInform Abstract: Synthesis of a 1,2-Dihydro[60]fullerylglycine Derivative by a Novel Cyclopropane Ring Opening of a Methano[60]fullerene.
β Scribed by Glenn A. Burley; Paul A. Keller; Stephen G. Pyne; Graham E. Ball
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Preparation and Structure of a Novel Methano(60)fullerene Containing a Stable P-Ylide. -Heating of C60-fullerene with PPh3 and dimethyl acetylenedicarboxylate in toluene gives the title compound in 61% yield, existing as 3:2 mixture of two rotational isomers. -(YAMAGUCHI,
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Ring Opening of the Heterocycle in (60)Fullereno(1,2-d)isoxazole. -N-O bond cleavage of easily available cycloadduct (I) opens a new route to the preparation of isomerically pure fullerol derivatives. -(IRNGARTINGER,