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ChemInform Abstract: Preparation and Structure of a Novel Methano(60)fullerene Containing a Stable P-Ylide.

✍ Scribed by H. YAMAGUCHI; S. MURATA; T. AKASAKA; T. SUZUKI

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199734111

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✦ Synopsis

Preparation and Structure of a Novel Methano(60)fullerene Containing a Stable P-Ylide.

-Heating of C60-fullerene with PPh3 and dimethyl acetylenedicarboxylate in toluene gives the title compound in 61% yield, existing as 3:2 mixture of two rotational isomers. -(YAMAGUCHI,

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