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ChemInform Abstract: Preparation of a [60]Fullerene Derivative Containing a Fused Seven-Membered Ring.

โœ Scribed by S. PYO; L. SHU; L. ECHEGOYEN


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Preparation and Str
โœ H. YAMAGUCHI; S. MURATA; T. AKASAKA; T. SUZUKI ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 28 KB ๐Ÿ‘ 1 views

Preparation and Structure of a Novel Methano(60)fullerene Containing a Stable P-Ylide. -Heating of C60-fullerene with PPh3 and dimethyl acetylenedicarboxylate in toluene gives the title compound in 61% yield, existing as 3:2 mixture of two rotational isomers. -(YAMAGUCHI,