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Preparation and characterization of a novel dumbbell-type [60]fullerene dimer containing a cyanine dye


Book ID
115502033
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
206 KB
Volume
25
Category
Article
ISSN
1144-0546

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A novel methanofullerene containing a stable phosphorous ylid is obtained from a reaction of fullerene (C60) with a 1:1 mixture of triphenylphosphine and dimethyl acetylenedicarboxylate.

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Preparation and Structure of a Novel Methano(60)fullerene Containing a Stable P-Ylide. -Heating of C60-fullerene with PPh3 and dimethyl acetylenedicarboxylate in toluene gives the title compound in 61% yield, existing as 3:2 mixture of two rotational isomers. -(YAMAGUCHI,