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Synthesis and transformation of a novel methano[60]fullerene having a formyl group

โœ Scribed by Masahiro Hamada; Tetsuo Hino; Kazushi Kinbara; Kazuhiko Saigo

Book ID
104231005
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
115 KB
Volume
42
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The reaction of [60]fullerene with a dimethylsulfonium a-formylalkylide gave a novel methano[60]fullerene having a formyl group at the bridge-head carbon. This 2,2-[60]fulleroalkanal was readily converted into a variety of N-aryl-2,2-[60]fulleroaldimines by condensation with aromatic amines; one of them showed efficient quenching of the fluorescence of the [60]fullerene core, due to a photoinduced intramolecular electron transfer.

๐Ÿ“œ SIMILAR VOLUMES

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

The First Synthesis of a Methano[60]full
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โœ Tomoyuki Tada; Yasuhiro Ishida; Kazuhiko Saigo ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons โš– 8 KB ๐Ÿ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.