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Poly[[μ3-4-(4,5-diazafluoren-9-ylideneamino)benzoato-κ3O,O′:N](methanol-κO)(thiocyanato-κN)cadmium(II)]

✍ Scribed by Zheng, Ju-Mei ;Du, Chen-Xia ;Wu, Yang-Jie

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 562 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807019460

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✦ Synopsis

In the crystal structure of the title compound, [Cd(C 18 H 10 NO 2 )(NCS)(CH 3 OH)] n , the Cd II atom is O,O 0chelated by the monoanionic carboxylate group and N,N 0chelated by the diazafluorene portion of a symmetry-related ligand. The geometry is seven-coordinate pentagonal bipyramidal. The crystal structure exhibits intermolecular O-HÁ Á ÁO hydrogen bonds.

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