The title polymeric compound, {[MnHg(SCN) 4 (H 2 O)]Á-C 4 H 8 O 2 S} n , consists of slightly distorted MnN 4 O 2 octahedra and HgS 4 tetrahedra. Each Mn II ion is bound to N atoms belonging to the thiocyanate (SCN) groups and to two O atoms of adjacent water ligands. The sulfolane molecule connects
Poly[[μ-aqua-tetra-μ-thiocyanato-cadmium(II)mercury(II)] sulfolane solvate]
✍ Scribed by Wang, Xin-Qiang ;Yu, Wen-Tao ;Hou, Xian-Qin ;Xu, Dong ;Geng, Yan-Ling
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 250 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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The title compound, {(C~10~H~16~N)[Cd(SCN)~3~]}~__n__~, contains [(C~6~H~5~CH~2~)N(CH~3~)~3~]^+^ cations lying between one-dimensional chains of stoichiometry {[Cd(SCN)~3~]^−^}~__n__~. Each Cd^II^ ion is 3__N__,3__S__-hexacoordinated by thiocyanate ligands, in an octahedral __fac__ arrangement. The
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.033 wR factor = 0.086 Data-to-parameter ratio = 20.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.