catena-Poly[[dipyridylcopper(II)]-di-μ-thiocyanato]
✍ Scribed by Chen, Guang ;Bai, Zhi-Ping ;Qu, Sheng-Ju
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 149 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In the title compound, [Cu(NCS)~2~(C~5~H~14~N~2~)]~__n__~, the Cu^II^ atom is five-coordinated in a square-pyramidal geometry, with two N atoms of the __N__,__N__-dimethylpropane-1,3-diamine ligand and two N atoms from two thiocyanate ligands defining the basal plane, and one S atom of another thioc
The title compound, {(C~10~H~16~N)[Cd(SCN)~3~]}~__n__~, contains [(C~6~H~5~CH~2~)N(CH~3~)~3~]^+^ cations lying between one-dimensional chains of stoichiometry {[Cd(SCN)~3~]^−^}~__n__~. Each Cd^II^ ion is 3__N__,3__S__-hexacoordinated by thiocyanate ligands, in an octahedral __fac__ arrangement. The
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.033 wR factor = 0.086 Data-to-parameter ratio = 20.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.