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catena-Poly[[(N,N-dimethyl­propane-1,3-diamine)thio­cyanato­copper(II)]-μ-thio­cyanato]

✍ Scribed by Wang, Chen-Yi

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
317 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Cu(NCS)~2~(C~5~H~14~N~2~)]~n~, the Cu^II^ atom is five-coordinated in a square-pyramidal geometry, with two N atoms of the N,N-dimethylpropane-1,3-diamine ligand and two N atoms from two thiocyanate ligands defining the basal plane, and one S atom of another thiocyanate ligand occupying the apical position. The [Cu(NCS)~2~(C~5~H~14~N~2~)] units are linked by bridging thiocyanate ligands, forming chains running along the b axis.

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Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.036 wR factor = 0.107 Data-to-parameter ratio = 14.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.