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catena-Poly[[(N,N-diethylethane-1,2-diamine)thiocyanatocopper(II)]-μ-thiocyanato]

✍ Scribed by Wang, Li-Hua ;Li, Li-Zhong

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
298 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Cu(NCS) 2 (C 6 H 16 N 2 )] n , is a thiocyanatebridged polynuclear copper(II) complex. The Cu II atom is five-coordinate in a square-pyramidal geometry, with two N atoms of the N,N-diethylethane-1,2-diamine ligand and two N atoms from two thiocyanate ligands defining the basal plane, and one S atom of another thiocyanate ligand occupying the apical position. The [Cu(NCS) 2 (C 6 H 16 N 2 )] units are linked by bridging thiocyanate ligands, forming chains running along the a axis.

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