catena-Poly[benzyltrimethylammonium [cadmium(II)-tri-μ2-thiocyanato]]
✍ Scribed by Bala, Ritu ;Kennedy, Alan R. ;Saneja, Kalpna ;Sharma, Raj Pal
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 229 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, {(C~10~H~16~N)[Cd(SCN)~3~]}~n~, contains [(C~6~H~5~CH~2~)N(CH~3~)~3~]^+^ cations lying between one-dimensional chains of stoichiometry {[Cd(SCN)~3~]^−^}~n~. Each Cd^II^ ion is 3__N__,3__S__-hexacoordinated by thiocyanate ligands, in an octahedral fac arrangement. The asymmetric unit contains two cations and two anions.
📜 SIMILAR VOLUMES
The title compound, {[(C 6 H 5 CH 2 )N(C 2 H 5 ) 3 ][Cd(SCN) 3 ]} n , contains benzyltriethylammonium cations lying between one-dimensional chains of stoichiometry {[Cd(SCN) 3 ] À } n . Each Cd 2+ ion is 3N,3S-hexacoordinated by thiocyanate ligands in an octahedral arrangement. The asymmetric unit c
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.033 wR factor = 0.086 Data-to-parameter ratio = 20.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Acta Cryst. (2005). E61, m1340-m1342 Yang et al. [Zn 2 (C 7 H 5 O 2 ) 3 (OH)] m1341 metal-organic papers m1342 Yang et al. [Zn 2 (C 7 H 5 O 2 ) 3 (OH)]