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catena-Poly[[aqua­diimidazole­cadmium(II)]-μ-thio­phene-2,5-dicarboxyl­ato]

✍ Scribed by Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
269 KB
Volume
62
Category
Article
ISSN
1600-5368

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In the molecule of the title compound, [CdCu~2~(C~8~H~3~O~5~)~2~(H~2~O)~2~]~__n__~, each 2-oxidobenzene-1,3-dicarboxylate trianion is bonded to two Cu atoms through O atoms of the carboxylates and the deprononated hydroxy group in chelating mode, forming [Cu~2~(C~8~H~3~O~5~)~2~]^2−^ units. A pair of

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The title hydrated 2,2 0 -bipyridine-6,6 0 -dicarboxylatecadmium(II) complex, {[Cd(C 12 H 2 N 2 O 4 )(H 2 O) 2 ]Á2H 2 O} n , crystallizes with eight oxygen-bridged monomer units in the unit cell. The divalent cadmium ion is seven-coordinate, and the coordination polyhedron can best be described as s