catena-Poly[[triaquacadmium(II)]-μ2-pyrazine-2,3-dicarboxylato]
✍ Scribed by Ma, Yi ;He, Yong-Ke ;Han, Zheng-Bo
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 236 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The title hydrated 2,2 0 -bipyridine-6,6 0 -dicarboxylatecadmium(II) complex, {[Cd(C 12 H 2 N 2 O 4 )(H 2 O) 2 ]Á2H 2 O} n , crystallizes with eight oxygen-bridged monomer units in the unit cell. The divalent cadmium ion is seven-coordinate, and the coordination polyhedron can best be described as s
In the molecule of the title compound, [CdCu~2~(C~8~H~3~O~5~)~2~(H~2~O)~2~]~__n__~, each 2-oxidobenzene-1,3-dicarboxylate trianion is bonded to two Cu atoms through O atoms of the carboxylates and the deprononated hydroxy group in chelating mode, forming [Cu~2~(C~8~H~3~O~5~)~2~]^2−^ units. A pair of