In the title compound, (C 2 H 8 N) 2 [Cu 2 (C 5 HN 2 O 4 ) 2 (H 2 O) 2 ]Á-H 2 O, the cations, anions and water molecules are linked by hydrogen bonds into a network structure. Two pyrazole-3,5dicarboxylate trianions and one water molecule are coordinated to the Cu II ion and the geometry is square-p
Poly[di-μ2-aqua-μ-pyrazole-3,5-dicarboxylato-copper(II)]
✍ Scribed by Han, Zheng-Bo ;Ma, Yong
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 232 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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In the molecule of the title compound, [CdCu~2~(C~8~H~3~O~5~)~2~(H~2~O)~2~]~__n__~, each 2-oxidobenzene-1,3-dicarboxylate trianion is bonded to two Cu atoms through O atoms of the carboxylates and the deprononated hydroxy group in chelating mode, forming [Cu~2~(C~8~H~3~O~5~)~2~]^2−^ units. A pair of
In the title coordination polymer, [Mn(HIDC)(H 2 O)] n (HIDC 2À is the 1H-imidazole-4,5-dicarboxylate dianion, C 5 H 2 N 2 O 4 ), each Mn II atom is in an octahedral coordination by one N atom and four carboxylate O atoms from three HIDC 2À anions, and one water molecule. The Mn II atoms are linked