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Poly[aqua­manganese(II)-μ3-1H-imidazole-4,5-dicarboxyl­ato]

✍ Scribed by Gao, Shan ;Huo, Li-Hua ;Zhao, Hui ;Liu, Ji-Wei

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
231 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title coordination polymer, [Mn(HIDC)(H 2 O)] n (HIDC 2À is the 1H-imidazole-4,5-dicarboxylate dianion, C 5 H 2 N 2 O 4 ), each Mn II atom is in an octahedral coordination by one N atom and four carboxylate O atoms from three HIDC 2À anions, and one water molecule. The Mn II atoms are linked by HIDC 2À anions into a layer structure. A threedimensional coordination network is formed by OÐHÁ Á ÁN and OÐHÁ Á ÁO hydrogen bonding.

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