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Poly[(μ-4-methyl­pyridine N-oxide)bis­(μ-thio­cyanato)cobalt(II)]

✍ Scribed by Zhang, Shi-Guo ;Li, Wei-Nan ;Shi, Jing-Min


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
325 KB
Volume
62
Category
Article
ISSN
1600-5368

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catena-Poly[[bis­(thio­cyanato-κN)cobalt
✍ Moitsheki, Lesego J. ;Bourne, Susan A. ;Nassimbeni, Luigi R. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 207 KB

Reaction of Co(NCS) 2 and 2-aminobenzonitrile (ABN) produces the title one-dimensional polymer, [Co(NCS) 2 -(ABN) 2 ] n , where ABN is 2-aminobenzonitrile (C 7 H 6 N 2 ). Octahedrally coordinated Co II ions are bridged by the ABN molecules, which are coordinated to the central metal via the N donors

catena-Poly[[bis(thiocyanato-κN)cobalt(I
✍ Springsteen, Caleb H. ;LaDuca, Robert L. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 943 KB

In the title compound, [Co(NCS)~2~(C~10~H~9~N~3~)], a Co^II^ atom with tetrahedral coordination is bound by two __N__-donor thiocyanate anions and two __N__-donor atoms from two crystallographically distinct di-4-pyridylamine (dpa) ligands whose central NH units lie on twofold axes. The dpa ligands