The title structure, [Co(-NCS) 2 (-C 6 H 7 NO 2 )] n , forms twodimensional sheets parallel to the ab plane in which both the thiocyanate and 4-methoxypyridine N-oxide ligands act as bridging ligands.
Poly[(μ-4-methylpyridine N-oxide)bis(μ-thiocyanato)cobalt(II)]
✍ Scribed by Zhang, Shi-Guo ;Li, Wei-Nan ;Shi, Jing-Min
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 325 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Reaction of Co(NCS) 2 and 2-aminobenzonitrile (ABN) produces the title one-dimensional polymer, [Co(NCS) 2 -(ABN) 2 ] n , where ABN is 2-aminobenzonitrile (C 7 H 6 N 2 ). Octahedrally coordinated Co II ions are bridged by the ABN molecules, which are coordinated to the central metal via the N donors
In the title compound, [Co(NCS)~2~(C~10~H~9~N~3~)], a Co^II^ atom with tetrahedral coordination is bound by two __N__-donor thiocyanate anions and two __N__-donor atoms from two crystallographically distinct di-4-pyridylamine (dpa) ligands whose central NH units lie on twofold axes. The dpa ligands