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Polymerization of 3-methoxy-3-phenylpropene with VCl3-AlEt3: Analysis of the side-reactions contributing to the understanding of the mechanism of Ziegler-Natta reaction

✍ Scribed by J.G. Rodriguez; F. Carreño; C. Fernandez-Sanchez; R. Alcantara

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
237 KB
Volume
25
Category
Article
ISSN
0014-3057

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✦ Synopsis

Polymerization of 3-methoxy-3-phenylpropene has been carried out with the VCI3-AIE b catalyst system, under various experimental conditions. Coordination of the methoxyl group on the transition metal catalyst is showed through a [3,3] methoxylotropic rearrangement of the monomer. l-methoxy-l-phenylpentane and 1-chloro-l-phenylpentane were also isolated as reaction products.

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