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Ziegler-natta polymerization of styrene and 2-vinylpyridine with the homogeneous catalyst AlEt3 VCl4: influence of heteroaromatic bases

✍ Scribed by D. Fernandez-Moreno; C. Fernandez-Sanchez; J.G. Rodriguez; A. Alberola

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
449 KB
Volume
25
Category
Article
ISSN
0014-3057

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✦ Synopsis

A~traet--Polymerizations of styrene and 2-vinylpyridine were undertaken with AIEh-VCI 4 as homogeneous catalyst, under several sets of conditions. Conversion was related to the formation time of the catalytic species. Relative crystallinity and average molecular weight for the polymers obtained at 25", 50 °, and 90 ° are given. Influences of donor ligands such as pyridine and 2-and 4-methylpyridine on the polymerizations have been considered.

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