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Polymer-supported chiral phosphinooxazolidine ligands for palladium-catalyzed asymmetric allylic alkylations and Diels–Alder reactions

✍ Scribed by Hiroto Nakano; Kouichi Takahashi; Reiko Fujita

Book ID: 108283958
Publisher: Elsevier Science
Year: 2005
Tongue: English
Weight: 176 KB
Volume: 16
Category: Article
ISSN: 0957-4166
DOI: 10.1016/j.tetasy.2005.05.017

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reactions of 1,3diphenyl-2-propenyl acetate (II). Best results are obtained with derivative (Ia). Dimethyl malonate as nucleophile gives the product (IV) with high e.e., whereas benzylamine provides only moderate stereoselectivity. -(JIN, MYUNG-