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Polymer-Supported Chiral Phosphinooxazolidine Ligands for Pd-Catalyzed Asymmetric Allylic Substitution.

✍ Scribed by Young-Mok Kim; Myung-Jong Jin

Publisher
John Wiley and Sons
Year
2005
Weight
15 KB
Volume
36
Category
Article
ISSN
0931-7597

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reactions of 1,3diphenyl-2-propenyl acetate (II). Best results are obtained with derivative (Ia). Dimethyl malonate as nucleophile gives the product (IV) with high e.e., whereas benzylamine provides only moderate stereoselectivity. -(JIN, MYUNG-