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Chiral Thiazoline Ligands: Application in Pd-Catalyzed Allylic Substitution.

✍ Scribed by Isabelle Abrunhosa; Lise Delain-Bioton; Annie-Claude Gaumont; Mihaela Gulea; Serge Masson


Publisher
John Wiley and Sons
Year
2005
Weight
152 KB
Volume
36
Category
Article
ISSN
0931-7597

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Application of SDP Ligands for Pd-Cataly
✍ Jian-Hua Xie; Hai-Feng Duan; Bao-Min Fan; Xu Cheng; Li-Xin Wang; Qi-Lin Zhou πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 145 KB πŸ‘ 2 views

## Abstract Chiral spiro diphosphines (SDP) are efficient ligands for the Pd‐catalyzed asymmetric allylic alkylation of 1,3‐diphenyl‐2‐propenyl acetate with dimethyl malonate and related nucleophiles. The newly synthesized ligand DMM‐SDP (**1e**) with 3,5‐dimethyl‐4‐methoxy groups on the __P__‐phen