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Chiral Phosphinooxazolidine Ligands for Palladium- and Platinum-Catalyzed Asymmetric Diels−Alder Reactions

✍ Scribed by Nakano, Hiroto; Takahashi, Kouichi; Okuyama, Yuko; Senoo, Chieko; Tsugawa, Natsumi; Suzuki, Yuichiro; Fujita, Reiko; Sasaki, Kazuo; Kabuto, Chizuko


Book ID
126460010
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
215 KB
Volume
69
Category
Article
ISSN
0022-3263

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New chiral phosphinooxazolidine ligands
✍ Myung-Jong Jin; Jung-Ae Jung; Sang-Han Kim 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 115 KB

New chiral phosphinooxazolidines were prepared and examined as chiral ligands in Pd-catalyzed asymmetric allylic substitution reaction of 1,3-diphenyl-2propenyl acetate with dimethyl malonate or benzylamine. Enantioselectivity up to 9896 was observed.