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New chiral phosphinooxazolidine ligands for palladium-catalyzed asymmetric allylic substitution

✍ Scribed by Myung-Jong Jin; Jung-Ae Jung; Sang-Han Kim

Book ID: 104261719
Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 115 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)00936-3

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✦ Synopsis

New chiral phosphinooxazolidines were prepared and examined as chiral ligands in Pd-catalyzed asymmetric allylic substitution reaction of 1,3-diphenyl-2propenyl acetate with dimethyl malonate or benzylamine. Enantioselectivity up to 9896 was observed.

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