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Palladium-Catalyzed Asymmetric Allylic Substitution Reactions Using New Chiral Phosphinooxathiane Ligands

✍ Scribed by Nakano, Hiroto; Okuyama, Yuko; Yanagida, Mariko; Hongo, Hiroshi

Book ID: 120178207
Publisher: American Chemical Society
Year: 2001
Tongue: English
Weight: 155 KB
Volume: 66
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo001245x

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New chiral phosphinooxazolidines were prepared and examined as chiral ligands in Pd-catalyzed asymmetric allylic substitution reaction of 1,3-diphenyl-2propenyl acetate with dimethyl malonate or benzylamine. Enantioselectivity up to 9896 was observed.