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Chiral Phosphinooxazolidine Ligands for Palladium- and Platinum-Catalyzed Asymmetric Diels—Alder Reactions.

✍ Scribed by Hiroto Nakano; Kouichi Takahashi; Yuko Okuyama; Chieko Senoo; Natsumi Tsugawa; Yuichiro Suzuki; Reiko Fujita; Kazuo Sasaki; Chizuko Kabuto

Publisher
John Wiley and Sons
Year
2005
Weight
47 KB
Volume
36
Category
Article
ISSN
0931-7597

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reactions of 1,3diphenyl-2-propenyl acetate (II). Best results are obtained with derivative (Ia). Dimethyl malonate as nucleophile gives the product (IV) with high e.e., whereas benzylamine provides only moderate stereoselectivity. -(JIN, MYUNG-