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Phenyl­(pyrrolinedi­thio­carbamato)­mercury(II)

✍ Scribed by Lai, Chian Sing ;Tiekink, Edward R. T.

Book ID
104479842
Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
177 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis

An approximately linear geometry around Hg is found in the title compound, PhHg[S 2 CN(CH 2 ) 4 ] or [Hg(C 6 H 5 )(C 5 H 8 -NS 2 )]. Distortions in the geometry arise from intra-and intermolecular HgÁ Á ÁS interactions, with the latter resulting in the formation of loosely associated dimeric units.

📜 SIMILAR VOLUMES

Bis(μ-N-methyl-N-phenyl­di­thio­carbamat
Bis(μ-N-methyl-N-phenyl­di­thio­carbamato)[bis(N-methyl-N-phenyl­di­thio­carbamato)­zinc(II)]
✍ Baba, Ibrahim ;Lee, Lay Hoon ;Farina, Yang ;Othman, A. Hamid ;Ibrahim, Abdul Raz 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 246 KB

Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.047 wR factor = 0.114 Data-to-parameter ratio = 21.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

(N-Ethyl-N-propyl­di­thio­carbamato)­tri
(N-Ethyl-N-propyl­di­thio­carbamato)­tri­phenyl­tin(IV)
✍ Sanuddin, M. ;Farina, Yang ;Yamin, Bohari M. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 192 KB

Single-crystal X-ray study T = 273 K Mean '(C±C) = 0.005 A Ê R factor = 0.028 wR factor = 0.063 Data-to-parameter ratio = 19.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

(N-Cyclo­hexyl-N-methyl­di­thio­carbamat
(N-Cyclo­hexyl-N-methyl­di­thio­carbamato)­tri­phenyl­tin(IV)
✍ Awang, Normah ;Baba, Ibrahim ;Yusof, M. Sukeri M. ;Yamin, Bohari M. 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 172 KB

resulting white precipitate was ®ltered, washed with cold ethanol and dried in vacuo. Crystals suitable for X-ray analysis were obtained by recrystallization from a 1:1 mixture of ethanol and chloroform.

(N-Cyclo­hexyl-N-ethyl­di­thio­carbamato
(N-Cyclo­hexyl-N-ethyl­di­thio­carbamato)­tri­phenyl­tin(IV)
✍ Awang, Normah ;Baba, Ibrahim ;Yusof, M. Sukeri M. ;Yamin, Bohari M. 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 181 KB

The title compound, [Sn(C 6 H 5 ) 3 {S 2 CN(Et)C 6 H 11 }], has a similar geometry to its methyl analogue, between tetrahedral and distorted trigonal bipyramidal but closer to the latter. The long intramolecular SnÁ Á ÁS interaction of 2.9426 (10) A Ê is slightly shorter than in its methyl analogue,