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Phenyl Participation in the Solvolysis of Organomercurials

โœ Scribed by Jensen, Frederick R.; Ouellette, Robert J.

Book ID
127217333
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
136 KB
Volume
85
Category
Article
ISSN
0002-7863

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THE rates of solvolysis sensitive to changes In vides a dramatic way of of organomercurials are exceedingly structure, 1 and this reaction prodemonstrating anchimeric assistance. RHg+Y--> R+ + Hg' + Y-Thus, the rates of reaction are greatly enhanced by phenyl

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In a report on the stereochemistry and direction of cleavage of bicyclo[n.l.O]alkanes by lead tetraacetate and thallium triacetate (2), we suggested that 1,3-acetoql participation in the decomposition of the intermediate organometallic derivatives of the general structure I might be important.