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Neighboring group participation in solvolysis. IX.1 methyl participation in solvolysis of pinacolyl brosylate

✍ Scribed by Takashi Ando; Hisao Morisaki


Book ID
108384700
Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
134 KB
Volume
20
Category
Article
ISSN
0040-4039

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Neighboring group participation in solvo
✍ Takashi Ando; Nobuaki Shimizu; Sueng-Geon Kim; Yuho Tsuno; Yasuhide Yukawa πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 French βš– 213 KB

In recent years solvolysis of 2-arylethyl arenesulfonates has been successfully discussed based on the idea that the reaction proceeds via two discrete and competing paths designated as k, and ks. 2-5 While electrondonating substituents accelerate the reaction mainly or almost exclusively by the an