Neighboring group participation in solvolysis. VI. Methyl participation in acetolysis of neopentyl p-nitrobenzenesulfonate
β Scribed by Takashi Ando; Hiroshi Yamataka; Junjiro Kuramochi; Junko Yamawaki; Yasuhide Yukawa
- Book ID
- 108382090
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 125 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
As shown by kinetic and product analysis, the solvolysis of7 and 8 in m includes several competitive reactions, one of them being neighbofing sulfur participation and formation of intermediate cyclic sulfonium cation. Recently we have demonstrated' the absence of r-or n-participation in solvolysis o
In recent years solvolysis of 2-arylethyl arenesulfonates has been successfully discussed based on the idea that the reaction proceeds via two discrete and competing paths designated as k, and ks. 2-5 While electrondonating substituents accelerate the reaction mainly or almost exclusively by the an