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Neighboring sulfur participation in the solvolysis of 2-(ω-alkylthioalkyl)-3-methyl-2-cyclohexenyl p-nitrobenzoates

✍ Scribed by Mladen Ladika; Branko Juršić; Zlatko Mihalić; Dionis E. Sunko


Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
268 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis


As shown by kinetic and product analysis, the solvolysis of7 and 8 in m includes several competitive reactions, one of them being neighbofing sulfur participation and formation of intermediate cyclic sulfonium cation. Recently we have demonstrated' the absence of r-or n-participation in solvolysis of esters l-4.


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