In a report on the stereochemistry and direction of cleavage of bicyclo[n.l.O]alkanes by lead tetraacetate and thallium triacetate (2), we suggested that 1,3-acetoql participation in the decomposition of the intermediate organometallic derivatives of the general structure I might be important.
σ-carbon participation in the solvolysis of organomercurials
✍ Scribed by Frederick R. Jensen; Robert J. Ouellette; Gale Knutson; Donald A. Babbe
- Publisher
- Elsevier Science
- Year
- 1963
- Tongue
- French
- Weight
- 150 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
THE rates of solvolysis sensitive to changes In vides a dramatic way of of organomercurials are exceedingly structure, 1 and this reaction prodemonstrating anchimeric assistance. RHg+Y--> R+ + Hg' + Y-Thus, the rates of reaction are greatly enhanced by phenyl
📜 SIMILAR VOLUMES
Studies with the J-butyldimethylsulfonium ion give evidence for nucleophilic participation in the solvolyses of t-butyl compounds but electrophilic assistance would be the dominant factor for J.-butyl chloride solvolysis.
## Abstract The solvolysis rate constants __k__ for the 6‐__endo__‐substituted 2‐__exo__‐norbornyl toluenesulfonates **7** have been determined. Values of log__k__ correlate well with the respective inductive constants of the substitutents except when the latter are nucleophilic and therefore lead