THE rates of solvolysis sensitive to changes In vides a dramatic way of of organomercurials are exceedingly structure, 1 and this reaction prodemonstrating anchimeric assistance. RHg+Y--> R+ + Hg' + Y-Thus, the rates of reaction are greatly enhanced by phenyl
Nucleophilic participation in the solvolysis of the t-butyldimethylsulfonium ion
โ Scribed by Dennis N Kevill; Wan Ahmad Kamil; Steven W Anderson
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 265 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Studies with the J-butyldimethylsulfonium ion give evidence for nucleophilic participation in the solvolyses of t-butyl compounds but electrophilic assistance would be the dominant factor for J.-butyl chloride solvolysis.
๐ SIMILAR VOLUMES
In a report on the stereochemistry and direction of cleavage of bicyclo[n.l.O]alkanes by lead tetraacetate and thallium triacetate (2), we suggested that 1,3-acetoql participation in the decomposition of the intermediate organometallic derivatives of the general structure I might be important.
The kinetics of the solvolysis of the ion trans-[Coen2N3C11' have been investigated a t several temperatures in mixtures of water with t-butyl alcohol with concentrations of the latter ranging up to 50 vol% or a mol fraction of 0.16. Values for the enthalpy and entropy of activation show sharp chang