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Nucleophilic participation in the solvolysis of the t-butyldimethylsulfonium ion

โœ Scribed by Dennis N Kevill; Wan Ahmad Kamil; Steven W Anderson


Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
265 KB
Volume
23
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Studies with the J-butyldimethylsulfonium ion give evidence for nucleophilic participation in the solvolyses of t-butyl compounds but electrophilic assistance would be the dominant factor for J.-butyl chloride solvolysis.


๐Ÿ“œ SIMILAR VOLUMES


ฯƒ-carbon participation in the solvolysis
โœ Frederick R. Jensen; Robert J. Ouellette; Gale Knutson; Donald A. Babbe ๐Ÿ“‚ Article ๐Ÿ“… 1963 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 150 KB

THE rates of solvolysis sensitive to changes In vides a dramatic way of of organomercurials are exceedingly structure, 1 and this reaction prodemonstrating anchimeric assistance. RHg+Y--> R+ + Hg' + Y-Thus, the rates of reaction are greatly enhanced by phenyl

1,3-acetoxyl participation in the solvol
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In a report on the stereochemistry and direction of cleavage of bicyclo[n.l.O]alkanes by lead tetraacetate and thallium triacetate (2), we suggested that 1,3-acetoql participation in the decomposition of the intermediate organometallic derivatives of the general structure I might be important.

Kinetics of the solvolysis of the trans-
โœ Ali E. Eid; Cecil F. Wells ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 525 KB

The kinetics of the solvolysis of the ion trans-[Coen2N3C11' have been investigated a t several temperatures in mixtures of water with t-butyl alcohol with concentrations of the latter ranging up to 50 vol% or a mol fraction of 0.16. Values for the enthalpy and entropy of activation show sharp chang