THE rates of solvolysis sensitive to changes In vides a dramatic way of of organomercurials are exceedingly structure, 1 and this reaction prodemonstrating anchimeric assistance. RHg+Y--> R+ + Hg' + Y-Thus, the rates of reaction are greatly enhanced by phenyl
1,3-acetoxyl participation in the solvolysis of organomercury compounds
β Scribed by Robert J. Ouellette; Richard D. Robins
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 119 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
In a report on the stereochemistry and direction of cleavage of bicyclo[n.l.O]alkanes by lead tetraacetate and thallium triacetate (2), we suggested that 1,3-acetoql participation in the decomposition of the intermediate organometallic derivatives of the general structure I might be important.
π SIMILAR VOLUMES
Studies with the J-butyldimethylsulfonium ion give evidence for nucleophilic participation in the solvolyses of t-butyl compounds but electrophilic assistance would be the dominant factor for J.-butyl chloride solvolysis.
As shown by kinetic and product analysis, the solvolysis of7 and 8 in m includes several competitive reactions, one of them being neighbofing sulfur participation and formation of intermediate cyclic sulfonium cation. Recently we have demonstrated' the absence of r-or n-participation in solvolysis o